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Download e-book for iPad: Application of Ionic Liquids on Rare Earth Green Separation by Ji Chen

By Ji Chen

ISBN-10: 366247509X

ISBN-13: 9783662475096

This ebook comprehensively info the functions of ionic beverages in infrequent earth eco-friendly separation and usage in keeping with the original interactions of ionic beverages with infrequent earth ions. It includes 9 chapters demonstrating the synthesis and houses of ionic beverages, coordination chemistry of ionic beverages and infrequent earth, ionic beverages as diluents, extractants, adsorption resins for infrequent earth extraction and separation, electrodeposition of infrequent earth metals in ionic drinks, and coaching of infrequent earth fabric using ionic beverages. it's either fascinating and invaluable to chemists, metallurgists and graduate scholars engaged on basic study of ionic beverages in addition to pros within the infrequent earth undefined. It presents huge insights into eco-friendly chemistry and sustainable procedures for infrequent earth separation to be able to meet the environmental problem of infrequent earth metallurgy world wide, particularly in China.

Ji Chen is a Professor of Chemistry on the Changchun Institute of utilized Chemistry, chinese language Academy of Sciences, China.

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The separation community has recognized combining ILs as a strategy for tuning their physicochemical properties [70], but there does not yet appear to be any consideration for how dissolution of charged metal complexes may change the interactions with the constituents of IL. Oppositely charged metal complexes may have an electrostatic interaction which prevents their effective separation. To illustrate this phenomenon, we present the crystal structure of [Tb(NO3)2(OH2)5][Th(NO3)5(OH2)2] · H2O. This compound was prepared by evaporating a solution of Tb(NO3)3 · 5H2O and Th(NO3)4 · 4H2O in methanol.

Royal Society of Chemistry, Cambridge, pp 155–180 3. Rare earth elements: A review of production, processing, recycling, and associated environmental issues (2012) U. S. Environmental Protection Agency National Service Center for Environmental Publications. pdf. Accessed 17 Feb 2015 4. Visser AE, Rogers RD (2003) Room-temperature ionic liquids: New solvents for f-element separations and associated solution chemistry. J Solid State Chem 171:109–113 5. Earle MJ, Seddon KR (2000) Ionic liquids. Green solvents for the future.

In light of these potential challenges, many countries will have to rely on recycling REEs from pre-consumer scrap, industrial residues, and REE-containing end-of-life products [1, 5]. Over the course of the last two decades, ionic liquids (ILs) have been increasingly used to separate REEs in the recycling process [6–12]. ILs are a class of molten salts that are liquid at temperatures below 100  C [13]. ILs are amenable to the recycling of REEs because the cation and anion components are readily tailored to a given process, and they offer numerous advantages over typical organic solvents, such as low volatility, low flammability, a broad temperature range of stability, the ability to dissolve both inorganic and organic compounds, high conductivity, and wide electrochemical windows [14].

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Application of Ionic Liquids on Rare Earth Green Separation and Utilization by Ji Chen


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